The longitudinal diffusion coefficients $D_L$ in the range of 0.1 to 1.5 kV/cm can be expressed as defined by the Einstein relation \[ D_L=\frac{\mu\epsilon_L}{e}=\left(\frac{a_0+a_1E+a_2E^{3/2}+a_3E^{5/2}}{1+(a_1/a_0)E+a_4E^2+a_5E^3}\right)\left(\frac{b_0+b_1E+b_2E^2}{1+(b_1/b_0)E+b_3E^2}\right)\left(\frac{T}{T_0}\right)^{-3/2}\left(\frac{T}{T_1}\right), \] with the parameters given previously.
The transverse diffusion coefficients $D_T$ is related to $D_L$ by: \[ \frac{D_L}{D_T} = 1+ \frac{E}{\mu}\frac{\partial \mu}{\partial E} \] The corresponding diffusion length can be calculated from the drift time $t$ by: \[ \sigma = \sqrt{2Dt} \]
For the detection of the ionization charge in LArTPCs, electron attachment to impurities in LAr (such as water or oxygen) is a source of signal attenuation, given that the drift velocity of ions is about five orders of magnitude lower than that of electrons. The mean lifetime ($\tau_A$) of electron cluster is given by: \[ \tau_A = \frac{1}{k_A n}, \] where $k_A$ is the attachment rate constant and $n$ is the concentration of the impurity.
The electron attachment rate constant ($k_A$) is an integral over energy of the product of the drifting election energy distribution function and the cross section for the attachment of the electron to an impurity molecule, both of which are functions of the drifting electron energy. Therefore, $k_A$ is a function of the external electric field. For electric fields below ~100 V/cm, the electrons are in thermal equilibrium with the liquid and in this region the attachment rate is independent of the electric field .
In Ref [2], the electron attachment rate data is fit with a constrained rational polynomial: \[ k_A=10^p \frac{a_1/b_1+a_1E+a_2E^{2}+a_3E^{3}+a_4E^{4}}{1+b_1E+b_2E^{2}+b_3E^{3}+b_4E^{4}}, \] where E is the electric field in units of kV/cm and $k_A$ is the attachment rate constant in units of s$^{-1}$. The best-fit parameters for common impurities can be found in Table 2 of [2].